| 1 | Karin Mayr | AUT | 22,77 | Q |
| 2 | Sylviane Felix | FRA | 23,31 | Q |
| 3 | Yuliya Tabakova | RUS | 23,78 | |
| 4 | M. Vasarmidou | GRE | 23,80 | |
| Aksel Gurcan | TUR | DNF |
| 1 | Gabi Rockmeier | GER | 23,06 | Q |
| 2 | Nora Ivanova-Güner | TUR | 23,19 | Q |
| 3 | Fabe Dia | FRA | 23,51 | |
| 4 | O. Chalandyreva | RUS | 23,78 | |
| 5 | Sarah Reilly | IRL | 23,90 |
| 1 | Muriel Hurtis | FRA | 22,71 | Q |
| 2 | Yekaterina Tosheva-Mashova | BUL | 23,48 | Q |
| 3 | Ciara Sheehy | IRL | 23,62 | |
| 4 | Katrin Käärt | EST | 23,78 | |
| 5 | Anna Pacholak | POL | 24,06 |